ONE-DIMENSIONAL FERRO-MAGNETIC AND FERRI-MAGNETIC CHAINS MADE OF AN ALTERNATING ARRAY OF 1,3-BIS(N-TERT-BUTYL-N-OXYAMINO)BENZENE AND MN-II(HFAC)(2) (HHFAC=HEXAFLUOROACETYLACETONE)

被引:64
作者
INOUE, K [1 ]
IWAMURA, H [1 ]
机构
[1] UNIV TOKYO,GRAD SCH SCI,DEPT CHEM,BUNKYO KU,TOKYO 113,JAPAN
关键词
D O I
10.1039/c39940002273
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A black monoclinic crystal of 1,3-[(BUN)-N-t(O-.)](2C6H4MnII)-Mn-.(hfac)(2), for which the formation of one-dimensional chains by ligation of the bisnitroxide radical serving as a bidentate ligand to Mn-II(hfac)(2) has been disclosed by an X-ray crystal structure analysis, undergoes transition to a metamagnet at 5.5 K.
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页码:2273 / 2274
页数:2
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