Infrared chemiluminescence from hydrogen atom reactions with the sulfur-chlorine bond

被引：7

作者：

Johnson, R. L. ^{[1
]}

Setser, D. W. ^{[1
]}

机构：

[1] Kansas State Univ, Dept Chem, Manhattan, KS 66502 USA

来源：

CHEMICAL PHYSICS LETTERS | 1969年 / 3卷 / 04期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0009-2614(69)80027-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reaction of hydrogen atoms with SCl2, S2Cl2, SOCl2 and SO2Cl2 gives infrared chemiluminescence from HCl in high vibrational levels. The degree of relaxation from the initial distribution was estimated by comparison to the emission from the reaction of H + Cl-2. The vibrational level populations of HCl decreased in the series from SCl2 to SO2Cl2.

引用

页码：207 / 209

页数：3

共 7 条

[1] DISTRIBUTION OF REACTION PRODUCTS .3. C1+HI C1+DI
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POLANYI, JC
WONG, WH
WOODALL, KB
[J]. JOURNAL OF CHEMICAL PHYSICS, 1968, 49 (11) : 5189 - &
[2] VIBRATIONAL POPULATION-INVERSION AND STIMULATED EMISSION FROM CONTINUOUS-MIXING OF CHEMICAL REAGENTS
ANLAUF, KG
MAYLOTTE, DH
PACEY, PD
POLANYI, JC
[J]. PHYSICS LETTERS A, 1967, A 24 (04) : 208 - &
[3] ENERGY DISTRIBUTION AMONG REACTION PRODUCTS .2. H+X2 AND X+HY
ANLAUF, KG
KUNTZ, PJ
MAYLOTTE, DH
PACEY, PD
POLANYI, JC
[J]. DISCUSSIONS OF THE FARADAY SOCIETY, 1967, (44): : 183 - &
[4] INFRARED CHEMILUMINESCENCE FROM THE GASEOUS REACTION ATOMIC-H PLUS CL-2
CASHION, JK
POLANYI, JC
[J]. JOURNAL OF CHEMICAL PHYSICS, 1958, 29 (02) : 455 - 456
[5] FINLAY FD, 1964, CAN J CHEM, V42, P2176
[6] POLANYI JC, 1963, QUANT SPECTROSC RADI, V3, P471
[7] ROSSER RJ, 1960, J APPL CHEM-USSR, V10, P229

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