SYNTHESIS AND CHARACTERIZATION OF TWO NOVEL, NEST-SHAPED Mo-Cu-S CLUSTER COMPOUNDS, [MoOS(3)Cu(3)(Py)(5)X] (X = Br, I), AND THE SUBSTITUTION OF Mo-Cu-S CLUSTERS

被引：16

作者：

Hou Hongwei ^{[1
]}

Xin Xinquan ^{[1
]}

Lu Shaofang ^{[2
]}

Huang Xiaoxing ^{[2
]}

Wu Qiangjin ^{[2
]}

机构：

[1] Nanjing Univ, Dept Chem, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 1995年 / 35卷 / 3-4期

基金：

中国国家自然科学基金;

关键词：

Mo-Cu-S clusters; synthesis; substitution reaction; X-ray structure;

D O I：

10.1080/00958979508024041

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compounds [MoOS(3)Cu(3)(Py)(5)Br] (3) and [MoOS(3)Cu(3)(Py)(5)I] (4) were obtained through the nest-shaped cluster [(n-Bu)(4)N](2)[MoOS(3)Cu(3)BrCl(2)] (1) and twin-nest-shaped cluster [Et(4)N](4)[Mo(2) Cu(6)S(6)O(2)Br(2)I(4)](2) by reacting with pyridine. They show nest-shaped skeletons, and are characterized structurally by single-crystal X-ray analysis. These are the first neutral nest-shaped Mo(W)-Cu(Ag)-S clusters.

引用

页码：299 / 306

页数：8

共 12 条

[1]

Debray M. C. R., 1883, HEBD SEANCES ACAD SC, V96, P1616

[2] METAL-CLUSTERS IN BIOLOGY - QUEST FOR A SYNTHETIC REPRESENTATION OF THE CATALYTIC SITE OF NITROGENASE [J].

HOLM, RH .

CHEMICAL SOCIETY REVIEWS, 1981, 10 (04) :455-490

[3] SYNTHESIS, CRYSTAL-STRUCTURE AND NONLINEAR-OPTICAL PROPERTIES OF [NET4]4[CU6MO2S6O2BR2I4] [J].

HOU, HW ;

XIN, XQ ;

LIU, J ;

CHEN, MQ ;

SHU, S .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (22) :3211-3214

[4]

HOU HW, CHEM MAT IN PRESS

[5] SYNTHESES AND CHARACTERIZATION OF AMMONIUM AND TETRAALKYLAMMONIUM THIOMOLYBDATES AND THIOTUNGSTATES [J].

MCDONALD, JW ;

FRIESEN, GD ;

ROSENHEIN, LD ;

NEWTON, WE .

INORGANICA CHIMICA ACTA-ARTICLES, 1983, 72 (02) :205-210

[6]

MILLES CF, 1979, PHILOS T R SOC B, V299, P51

[7] DERIVATIVES OF TETRATHIOMETALLATES - SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF WS4(CU(PHEN))2 AND WS4PT(DPPM) [J].

POTVIN, C ;

MANOLI, JM ;

SECHERESSE, F ;

MARZAK, S .

INORGANICA CHIMICA ACTA, 1987, 134 (01) :9-12

[8] HETEROBIMETALLIC AGGREGATES DERIVED FROM THE DOUBLE CUBANE-LIKE STRUCTURE (NME4)4[MS4(CUCL)5CL2] (M=MO, W) [J].

SECHERESSE, F ;

ROBERT, F ;

MARZAK, S ;

MANOLI, JM ;

POTVIN, C .

INORGANICA CHIMICA ACTA, 1991, 182 (02) :221-228

[9] NEW NONLINEAR-OPTICAL CHROMOPHORE - SYNTHESIS, STRUCTURES, AND OPTICAL LIMITING EFFECT OF TRANSITION-METAL CLUSTERS (N-BU(4)N)(3)[WM(3)BR(4)S(4)] (M=CU AND AG) [J].

SHI, S ;

JI, W ;

LANG, JP ;

XIN, XQ .

JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (14) :3570-3572

[10] SYNTHESIS AND OPTICAL LIMITING CAPABILITY OF CUBANE-LIKE MIXED-METAL CLUSTERS (N-BU(4)N)(3)[MOAG(3)BRX(3)S(4)] (X=CL AND I) [J].

SHI, S ;

JI, W ;

TANG, SH ;

LANG, JP ;

XIN, XQ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (08) :3615-3616

← 1 2 →