UPHILL TRANSPORT OF AMINO-ACIDS THROUGH 2,3-EPITHIOPROPYL METHACRYLATE-2-ACRYLAMIDE-2-METHYL PROPANE SULFONIC-ACID COPOLYMER MEMBRANES

被引：9

作者：

NONAKA, T

TAKEDA, T

EGAWA, H

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Kumamoto University, Kumamoto-shi, 860

来源：

JOURNAL OF MEMBRANE SCIENCE | 1993年 / 76卷 / 2-3期

关键词：

UPHILL TRANSPORT; AMINO ACID TRANSPORT; CATION EXCHANGE MEMBRANES; 2-ACRYLAMIDE-2-METHYL PROPANE SULFONIC ACID; 2,3-EPITHIOPROPYL METHACRYLATE;

D O I：

10.1016/0376-7388(93)85217-K

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Cation exchange membranes were prepared with 2,3-epithiopropyl methacrylate (ETMA)-2-acrylamide-2-methyl propane sulfonic acid (AMPS) copolymers. Transport of amino acids such as glycine (H2NCH2COOH), phenylalanine [C6H5CH2CH(NH2)COOH], and lycine [H2N(CH2)4CH (NH2)COOH] through the membranes against their concentration gradient was investigated by using the system containing the amino acid-HCl on one side and the amino acid on the other side of the membrane under various conditions. The ETMA-AMPS copolymer membranes transported amino acids against their concentration gradient and the transport of amino acids depended on both the structure of the amino acids and the composition of the membranes. The transport rate was greatly affected by the H+ concentration at the amino acid-HCl side of the membrane. The transport mechanism is also discussed.

引用

页码：193 / 207

页数：15

共 14 条

[1] A theory of water and ionic solution, with particular reference to hydrogen and hydroxyl ions [J].