OXYGENATION OF ALKYLBENZENES, CATALYZED BY 10-METHYLACRIDINIUM ION VIA PHOTOINDUCED ELECTRON-TRANSFER UNDER VISIBLE-LIGHT IRRADIATION

被引：6

作者：

FUJITA, M

FUKUZUMI, S

机构：

[1] Osaka Univ, Osaka, Japan

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1994年 / 90卷 / 03期

关键词：

ALKYLBENZENES; ELECTRON TRANSFER; 10-METHYLACRIDINUM ION; OXYGENATION; PHOTOINDUCTION;

D O I：

10.1016/0304-5102(94)00030-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The efficient oxygenation of alkylbenzenes is initiated by photoinduced electron transfer from alkylbenzenes to the singlet excited state of 10-methylacridinium ion under visible light irradiation, followed by the deprotonation of alkylbenzene radical cations and the facile addition of oxygen to the deprotonated radicals, leading to the final oxygenated products.

引用

收藏

页码：L225 / L229

页数：5

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