DIELS-ALDER REACTION OF STYRENE WITH TRANS-PENTA-1,3-DIENE METHYL 2-TRANS,4-PENTADIENOATE AND DIMETHYL 2-TRANS,4-TRANS-HEXADIENEDIOATE

被引:4
作者
KORVER, O
KWA, TL
BOELHOUW.C
机构
[1] Laboratory for Chemical Technology, University of Amsterdam
关键词
D O I
10.1016/S0040-4020(01)82943-4
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The Diels-Alder reactions between styrene and trans-penta-1,3 -diene, methyl 2-trans,4-penta- dienoate and dimethyl 2-trans,4-trans-hexadienedioate are described.The structure of the following adducts was determined by means of IR and NMR spectrometry: trans-3-methyl-4-phenyl-cyclohex-1- ene,cis-3-methyl-4-phenyl-cyclohex-1-ene,trans-3-methyl-5-phenyl-cyclohex-1-ene,cis-3-methyl-5-phenyl- -cyclohex-1-ene, trans-3-carbomethoxy-4-phenyl-cyclohex-1-ene, cis-3-carbomethoxy-4-phenyl-cyclohex- 1-ene, 3-carbomethoxy-cis-4-phenyl-cis-6-carbomethoxy-cyclohex-1-ene and 3-carbomethoxy-trans-4- phenyl-cis-6-carbomethoxy-cyclohex-1-ene. © 1969.
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页码:4109 / &
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