SOLUTE SEGREGATION TO POINT-DEFECT SINKS IN NEUTRON-IRRADIATED NIMONIC-PE16

Nimonic PE16, a gamma-prime Ni3(Al,Ti) precipitate-strengthened alloy under consideration for fast reactor structural applications, has been neutron irradiated in three heat treatment conditions: solution treated, aged, and overaged. After irradiation at 600° C to 5.4 × 1022n/cm2 (E > 0.1 MeV), or 27 dpa, specimens were characterized for gamma-prime precipitate stability by transmission electron microscopy. The precipitate microstructures after irradiation reflected the influence of the preirradiation heat treatment; and indeed the precipitate particles present prior to irradiation remained stable. However, additional precipitation occurred during irradiation in each of the specimens examined. The in-reactor gamma-prime precipitation process decorated such microstructural features as voids, dislocations and carbide precipitates. Examples were found in the solution-treated condition where gamma prime in the form of Archimedes' screws had precipitated on climbing screw dislocations. The precipitation behavior observed is compared with predictions from existing models. It is concluded that models for solute diffusion to point-defect sinks and for Ostwald coarsening can account for the observations, but that the models for precipitate stability controlled by cascade dissolution during neutron irradiation do not. © 1979.