ELECTROCHEMICALLY CONTROLLED LIQUID-CHROMATOGRAPHY ON CONDUCTING POLYMER STATIONARY PHASES

被引:23
作者
GE, HL
WALLACE, GG
机构
[1] Chemistry Department, University of Wollongong, 1144
来源
JOURNAL OF LIQUID CHROMATOGRAPHY | 1990年 / 13卷 / 16期
关键词
D O I
10.1080/01483919008049099
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
Electrochemically controlled high performance liquid chromatography (EC/HPLC) using a conducting polymer stationary phase, has been investigated in the present paper. Polypyrrole coated reticulated vitreous carbon (RVC) particles have been employed as the stationary phase. Chromatographic characterization has been carried out using various molecular probes. The results indicate that chromatographic retention can be altered by the imposition of small electrical potentials on the stationary phase and that such effects can be used to improve the separation of certain compounds.
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页码:3245 / 3260
页数:16
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