OXYGEN EVOLUTION REACTION ON NIXCO(3-X)O4 ELECTRODES WITH SPINEL STRUCTURE

被引:53
作者
DECHIALVO, MRG
CHIALVO, AC
机构
[1] Programa de Electroquímica Aplicada e Ingeniería Electroquímica (PRELINE), Facultad de Ingeniería Química, 3000 Santa Fe
关键词
OXYGEN EVOLUTION; OXIDE ELECTRODES; CO-NI SPINEL; ELECTROCATALYTIC PROPERTIES;
D O I
10.1016/0013-4686(93)80105-9
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The oxygen evolution reaction on NixCo(3-x)O4 oxide electrodes with x values between 0.6 and 1.3 in alkaline solution was studied. The characterization of these oxides was carried out by X-ray diffraction, ir, XPS and SEM. The results obtained demonstrate the presence of the spinel structure on all types of electrodes studied and that the oxide, with a cobalt-nickel atomic surface ratio equal to two, has the maximum electrocatalytic activity.
引用
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页码:2247 / 2252
页数:6
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