AN ANALYTICAL ANALYSIS OF THE SQUARE-WELL FLUID BEHAVIORS

被引：70

作者：

TANG, YP

LU, BCY

机构：

[1] Department of Chemical Engineering, University of Ottawa, Ottawa

来源：

JOURNAL OF CHEMICAL PHYSICS | 1994年 / 100卷 / 09期

关键词：

D O I：

10.1063/1.467026

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Analytical expressions of the Helmholtz free energy, internal energy, and compressibility for the square-well fluid are developed from the first-order solution of the mean spherical approximation with further application of the Hilbert transform proposed previously. The developed expressions, including that of the first-order radial distribution function, are satisfactorily compared with the Monte Carlo simulation data available in the literature.

引用

页码：6665 / 6671

页数：7

共 22 条

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