CHEMISTRY OF CYANOACETYLENES .I. REACTIONS OF NITRILIUM IONS CONJUGATED WITH ACETYLENE

被引：11

作者：

SASAKI, T

EGUCHI, S

SHOJI, K

机构：

[1] Institute of Applied Organic Chemistry, Faculty of Engineering, Nagoya University, Chikusa-ku, Nagoya

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 03期

关键词：

D O I：

10.1039/j39690000406

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Although chlorocyanoacetylene is converted into an amide in sulphuric acid, cyanoacetylene itself is not. Nevertheless, both nitriles undergo the Ritter reaction with olefins and alcohols. N-(1,1-Dimethyl-2-chloroethyl)-propiolamide, one of the Ritter reaction products, gives an oxazoline on treatment with alkoxide, with accompanying addition of the alkoxide to the triple bond.

引用

页码：406 / &