Some reactions of 2-hydroxytestosterone and its diacetate. I

被引:29
作者
Clarke, Robert L.
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D O I
10.1021/ja01502a045
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Treatment of 2 beta-hydroxytestosterone diacetate (Ia) with p-toluenesulfonic acid in methanol produced 17 beta-hydroxy-5 alpha-androstan-3,6-dione. Oxidation of la, its 2 alpha-epimer Ib or 2 alpha-hydroxytestosterone with molecular oxygen under alkaline conditions gave 2,17 beta-dihydroxy-1,4-androstadien-3-one (IIIa).
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页码:4629 / 4631
页数:3
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