TRIETHYLALUMINUM CATALYZED RING-OPENING REACTION OF 1-ACETYL-2-[(TRIMETHYLSILYL)-METHYL]CYCLOBUTANES - STEREOSELECTIVE PREPARATION OF (Z)-ENOL TRIMETHYLSILYL ETHERS

被引：5

作者：

FUJIWARA, T

SUDA, A

TAKEDA, T

机构：

来源：

CHEMISTRY LETTERS | 1991年 / 09期

关键词：

D O I：

10.1246/cl.1991.1619

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The triethylaluminum catalyzed ring opening reaction of 1-acetyl-2-[(trimethylsilyl)methyl]cyclobutanes gave (Z)-6-(trimethylsiloxy)-1,5-heptadienes stereoselectively. The starting materials were easily prepared by the 1,4-addition of (trimethylsilyl)methylmagnesium chloride to 1-cyclobutenyl ketones.

引用

页码：1619 / 1622

页数：4

共 14 条

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