INTERMOLECULAR C-F AND INTRAMOLECULAR C-H ACTIVATION REACTION OF [RE(ETA(5)-C5ME5)(CO)3] WITH HEXAFLUOROBENZENE - CRYSTAL AND MOLECULAR-STRUCTURE OF [RE(ETA(6)-C5ME4CH2)(CO)2(C6F5)]

被引:56
作者
KLAHN, AH [1 ]
MOORE, MH [1 ]
PERUTZ, RN [1 ]
机构
[1] UNIV YORK,DEPT CHEM,YORK YO1 5DD,N YORKSHIRE,ENGLAND
关键词
D O I
10.1039/c39920001699
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Photochemical reaction of [Re(eta5-C5Me5)(CO)3] with hexafluorobenzene yields [Re(eta6-C5Me4CH2)(CO)2(CrF5)] formed by insertion into a C-F bond Of C6F6 and concomitant insertion into a methyl C-H bond; the reactions of [Re(eta6-C5Me4CH2)(CO2)(C6F5)] with PMe3 and with HCl show that the (eta6-C5Me4CH2) ligand is subject to both nucleophilic and electrophilic attack.
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页码:1699 / 1701
页数:3
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