FOAM FILMS AND SURFACE FORCE STUDIES OF AQUEOUS-SOLUTIONS OF OCTYL-BETA-GLUCOSIDE

被引:36
作者
WALTERMO, A
MANEV, E
PUGH, R
CLAESSON, P
机构
[1] INST SURFACE CHEM,S-11486 STOCKHOLM,SWEDEN
[2] UNIV SOFIA,FAC CHEM,DEPT PHYS CHEM,BU-1126 SOFIA,BULGARIA
关键词
D O I
10.1080/01932699408943558
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The interactions at the air/liquid and the liquid/solid interface have been studied for octyl-beta-glucoside. With the thin film balance the thickness of the equilibrium liquid films is determined as a function of surfactant concentration, inert salt concentration and pH. At high surfactant concentration and/or at low pH black films, about 4.6 nm thick, are formed. The stabilizing forces in the black films are related to the interactions within and between the layers. The forces acting between octyl-beta-glucoside surfactant layers adsorbed on hydrophobized mica were investigated with the interferometric type surface force apparatus. The forces measured between the sugar head-groups were dimethylamine oxide and monoglycerides. However, considerably more long-range repulsions are observed between surfactants with oligoethylene oxide head-groups.
引用
收藏
页码:273 / 296
页数:24
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