DOUBLE-HELICAL COMPLEXES FROM SIMPLE 2,2'/6',2''-TERPYRIDINES - THE CRYSTAL AND MOLECULAR-STRUCTURE [CU-2(PH(2)TPY)(2)][PF6](2) (PH(2)TPY=6,6''-DIPHENYL-2,2'/6',2''-TERPYRIDINE)

被引：57

作者：

CONSTABLE, EC ^{[1
]}

EDWARDS, AJ ^{[1
]}

HANNON, MJ ^{[1
]}

RAITHBY, PR ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CAMBRIDGE CTR MOLEC RECOGNIT,CHEM LAB,CAMBRIDGE CB2 1EW,CAMBS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 17期

关键词：

D O I：

10.1039/c39940001991

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

2,2':6',2''-Terpyridines form dinuclear complexes with copper(I) which are double-helical; the introduction of 6-phenyl substituents stabilises the helicate, and the crystal and molecular structure of [Cu-2(Ph(2)tpy)(2)][PF6](2) described.

引用

页码：1991 / 1992

页数：2

共 17 条

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[4] SELF-ASSEMBLY OF DOUBLE-HELICAL COMPLEXES OF 2,2'-6',2''-6'',2'''-QUATERPYRIDINE (QTPY) - THE X-RAY CRYSTAL-STRUCTURES OF [CU2(QTPY)2][PF6]2 AND [AG2(QTPY)2][BF4]2
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[9] THE STRUCTURE OF A DINUCLEAR COPPER(I) COMPLEX OF A SCHIFF-BASE LIGAND CONTAINING A COPPER COPPER BOND
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[10] Gisselbrecht J.-P., 1984, NOUV J CHIM, V8, P661

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