DOUBLE-HELICAL COMPLEXES FROM SIMPLE 2,2'/6',2''-TERPYRIDINES - THE CRYSTAL AND MOLECULAR-STRUCTURE [CU-2(PH(2)TPY)(2)][PF6](2) (PH(2)TPY=6,6''-DIPHENYL-2,2'/6',2''-TERPYRIDINE)

被引:57
作者
CONSTABLE, EC [1 ]
EDWARDS, AJ [1 ]
HANNON, MJ [1 ]
RAITHBY, PR [1 ]
机构
[1] UNIV CAMBRIDGE,CAMBRIDGE CTR MOLEC RECOGNIT,CHEM LAB,CAMBRIDGE CB2 1EW,CAMBS,ENGLAND
关键词
D O I
10.1039/c39940001991
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
2,2':6',2''-Terpyridines form dinuclear complexes with copper(I) which are double-helical; the introduction of 6-phenyl substituents stabilises the helicate, and the crystal and molecular structure of [Cu-2(Ph(2)tpy)(2)][PF6](2) described.
引用
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页码:1991 / 1992
页数:2
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