AQUEOUS-PHASE OXIDATIONS - THE INTRINSIC KINETICS OF SINGLE ORGANIC-COMPOUNDS

被引：50

作者：

WILLMS, RS ^{[1
]}

BALINSKY, AM ^{[1
]}

REIBLE, DD ^{[1
]}

WETZEL, DM ^{[1
]}

HARRISON, DP ^{[1
]}

机构：

[1] LOUISIANA STATE UNIV,DEPT CHEM ENGN,BATON ROUGE,LA 70803

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 1987年 / 26卷 / 01期

关键词：

CHEMICAL EQUIPMENT - Reactors - ORGANIC COMPOUNDS - Oxidation - OXYGEN - Concentration - PHENOLS - Oxidation;

D O I：

10.1021/ie00061a028

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The aqueous-phase oxidation of m-xylene and phenol has been studied in a batch autoclave reactor. Both reactions were characterized by an induction period during which little of the organic was oxidized, followed by a rapid reaction phase during which most of the organic was destroyed. The distribution of organic between vapor and liquid and interphase transfer caused by liquid-phase reaction and sampling were considered in the analysis of the data. Over the range of concentrations studied, the length of the induction period is independent of the organic concentration and inversely proportional to the dissolved oxygen concentration.

引用

页码：148 / 154

页数：7

共 16 条

[1]

BAILLOD CR, 1983, EPA600S283060 REP

[2]

BARONA N, 1979, HYDROCARBON PROC JUL, P179

[3]

CANNEY PJ, 1984, AICHE NAT M PHILADEL

[4]

Chowdhury A.K., 1975, AICHE SYM SER, V151, P46

[5] OXIDATION OF PROPIONIC-ACID SOLUTIONS [J].

DAY, DC ;

HUDGINS, RR ;

SILVESTO.PL .

CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 1973, 51 (06) :733-740

[6]

Denisova L. N., 1969, KINET KATAL, VX, P1244

[7] HIGH-TEMPERATURE MUTUAL SOLUBILITIES OF HYDROCARBONS AND WATER. [J].

Heidman, J.L. ;

Tsonopoulos, C. ;

Brady, C.J. ;

Wilson, G.M. .

AIChE Journal, 1985, 31 (03) :376-384

[8]

HELLING RK, 1981, DOE REPORT

[9]

Himmelblau D.M., 1960, J CHEM ENG DATA, V5, P10

[10] WET AIR OXIDATION OF SOLUBLE COMPONENTS IN WASTE-WATER [J].

PRUDEN, BB ;

LE, H .

CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 1976, 54 (04) :319-325

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