OXIDATIVELY INDUCED RADICAL CHEMISTRY OF DICARBONYL ETA-5-CYCLOPENTADIENYL IRON DERIVATIVES OF CARBOXYLIC-ACIDS (FP-ACYL COMPLEXES)

被引：4

作者：

AMIENS, C

BALAVOINE, G

GUIBE, F

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 20期

关键词：

D O I：

10.1039/c39910001458

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The 17-electron cationic [Fp-acyl] intermediates generated by cerium ammonium nitrate (CAN) oxidation of Fp-acyl complexes in dry acetonitrile undergo a fast homolytic dissociation leading to alkyl radical species whose subsequent fate is dependent on the structural features and reaction conditions.

引用

收藏

页码：1458 / 1460

页数：3

相关论文

共 12 条

[1] NUCLEOPHILIC REACTIVITY OF CARBON-CARBON DOUBLE BOND .3. A COMPARISON OF SOLVOLYTIC BEHAVIOR OF 5-HEXENYL AND CYCLOPENTYLCARBINYL P-NITROBENZENESULFONATES [J].

BARTLETT, PD ;

CLOSSON, WD ;

COGDELL, TJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (06) :1308-&

[2] SYNTHESIS, CHARACTERIZATION, AND REACTIONS OF (C5H5)(CO)2FE=C(CH3)2+ AND (C5H5)(CO)2FE=CH-CH=C(CH3)2+ [J].

CASEY, CP ;

MILES, WH ;

TUKADA, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (10) :2924-2931

[3]

GIESE B, 1986, RADICALS ORGANIC SYN, P141

[4]

GIESE B, 1986, RADICALS ORGANIC SYN, P77

[5] FREE-RADICAL CLOCKS [J].

GRILLER, D ;

INGOLD, KU .

ACCOUNTS OF CHEMICAL RESEARCH, 1980, 13 (09) :317-323

[6]

HEMDON JW, 1989, TETRAHEDRON LETT, V30, P6461

[7] NONENZYMIC BIOGENETIC-LIKE OLEFINIC CYCLIZATIONS [J].

JOHNSON, WS .

ACCOUNTS OF CHEMICAL RESEARCH, 1968, 1 (01) :1-&

[8] ELECTROCHEMICAL ACTIVATION OF ACYL LIGANDS IN ORGANOMETALS - ELECTRON-SPIN-RESONANCE STUDIES OF ACETYL COMPLEXES AND BENZOYLIRON(III) COMPLEXES [J].

KLINGLER, RJ ;

KOCHI, JK .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 202 (01) :49-63

[9] DETECTION AND CHARACTERIZATION OF RADICAL CATIONS RESULTING FROM THE OXIDATION OF METHYL AND ACETYL IRON COMPLEXES [J].

MAGNUSON, RH ;

ZULU, S ;

TSAI, WM ;

GIERING, WP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (22) :6887-6888

[10] UBER NITRILIUMSALZE .1. [J].

MEERWEIN, H ;

LAASCH, P ;

MERSCH, R ;

SPILLE, J .

CHEMISCHE BERICHTE-RECUEIL, 1956, 89 (02) :209-224