POLYMORPHISM OF (QUASI) 2-DIMENSIONAL MICELLES

被引:117
作者
ZHU, JY [1 ]
LENNOX, RB [1 ]
EISENBERG, A [1 ]
机构
[1] MCGILL UNIV,DEPT CHEM,801 SHERBROOKE ST W,MONTREAL H3A 2K6,QUEBEC,CANADA
关键词
D O I
10.1021/j100191a002
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Langmuir films of block polyelectrolyte surface aggregates formed at the air-water interface have been visualized as Langmuir-Blodgett films using transmission electron microscopy. The morphologies adopted by these (quasi) 2-D aggregates are critically dependent upon the ratio of the hydrophobic and hydrophilic block sizes. Three morphologies are observable (starfish, rod, and planar) in polystyrene/decylated poly(vinylpyridinium) block polyelectrolytes. Each particular morphology is observed within a well-defined composition range. Parallel polymorphism in 3D aggregates of block copolymers and small molecular weight amphiphiles suggest that the rules governing self-assembly in 2D and 3D and both small and large molecular weight molecules are qualitatively quite similar.
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收藏
页码:4727 / 4730
页数:4
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