AN EXPEDITIOUS STEREOSELECTIVE SYNTHESIS OF FUNCTIONALIZED 7-MEMBERED CARBOCYCLES BY REACTION OF 2-AMINOBUTA-1,3-DIENES WITH VINYLCHROMIUM FISCHER TYPE CARBENES

被引:34
作者
BARLUENGA, J [1 ]
AZNAR, F [1 ]
MARTIN, A [1 ]
GARCIAGRANDA, S [1 ]
SALVADO, MA [1 ]
PERTIERRA, P [1 ]
机构
[1] UNIV OVIEDO, FAC QUIM, DEPT QUIM FIS & ANALIT, E-33071 OVIEDO, SPAIN
关键词
D O I
10.1039/c39930000319
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The reaction between 2-aminobuta-1,3-dienes and pentacarbonyl-[1-methoxy-trans-3-(2-furyl)-prop-2-enylidene]-chromium-(0) takes place at room temperature leading with total regio- and stereo-selectivity to functionalized seven-membered carbocycles with good yields.
引用
收藏
页码:319 / 321
页数:3
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