SOLUTION AND SOLID-STATE INTERACTIONS OF C-60 WITH SUBSTITUTED ANILINES

被引：70

作者：

SIBLEY, SP

CAMPBELL, RL

SILBER, HB

机构：

[1] San Jose State Univ, San Jose, CA

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1995年 / 99卷 / 15期

关键词：

D O I：

10.1021/j100015a007

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The equilibrium constant for complexation of C-60 and aniline in toluene has been determined by UV/wis spectroscopy, with a value of K = 0.28 +/- 0.04 obtained. The first extracted and well-defined charge-transfer (CT) bands have been observed for complexes of Csa with a variety of aromatic amines, with CT band maxima moving to higher frequency with increasing amine ionization potential. FTIR spectra of solid C-60 With substituted anilines show slight blue shifts in C-60 bands, indicative of a small amount of donor-acceptor interaction.

引用

页码：5274 / 5276

页数：3

共 21 条

[1] CHARACTERIZATION OF THE SOLUBLE ALL-CARBON MOLECULES C60 AND C70 [J].

AJIE, H ;

ALVAREZ, MM ;

ANZ, SJ ;

BECK, RD ;

DIEDERICH, F ;

FOSTIROPOULOS, K ;

HUFFMAN, DR ;

KRATSCHMER, W ;

RUBIN, Y ;

SCHRIVER, KE ;

SENSHARMA, D ;

WHETTEN, RL .

JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (24) :8630-8633

[2]

BENESI HA, 1949, J AM CHEM SOC, V71, P2705

[3] VIBRATIONAL RAMAN AND INFRARED-SPECTRA OF CHROMATOGRAPHICALLY SEPARATED C60 AND C70 FULLERENE CLUSTERS [J].

BETHUNE, DS ;

MEIJER, G ;

TANG, WC ;

ROSEN, HJ ;

GOLDEN, WG ;

SEKI, H ;

BROWN, CA ;

DEVRIES, MS .

CHEMICAL PHYSICS LETTERS, 1991, 179 (1-2) :181-186

[4]

Connors K. A., 1987, BINDING CONSTANTS ME

[5] PROBING C-60 [J].

CURL, RF ;

SMALLEY, RE .

SCIENCE, 1988, 242 (4881) :1017-1022

[6]

DRESSELHAUS MS, 1993, J MATER RES, V8, P2068

[7] PI-SYSTEMS IN 3 DIMENSIONS [J].

FOWLER, PW ;

WOOLRICH, J .

CHEMICAL PHYSICS LETTERS, 1986, 127 (01) :78-83

[8]

HINDAWEY AM, 1980, INDIAN J CHEM A, V19, P615

[9]

KOBAYASHI T, 1974, B CHEM SOC JPN, V47, P2565

[10] C-60 - BUCKMINSTERFULLERENE [J].

KROTO, HW ;

HEATH, JR ;

OBRIEN, SC ;

CURL, RF ;

SMALLEY, RE .

NATURE, 1985, 318 (6042) :162-163

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