SOLUTION PROPERTIES OF COPOLYAMIDES

被引:4
作者
ALI, S
机构
[1] School of Textile Engineering, Georgia Institute of Technology, Atlanta
关键词
D O I
10.1016/0014-3057(79)90096-X
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Mark-Houwink-Sakurada relations for random copolymers from para-aminobenzoic acid and 6-aminohexanoic acid were determined in N,N-dimethylacetamide, dichloroacetic acid and trifluoroacetic acid. Unperturbed chain dimensions, solvent-polymer interaction parameters and conformational parameter, δ, were obtained by using the Stockmayer-Fixman equation. The unperturbed dimensions were also calculated by using a semi-empirical relation of Krigbaum; they compare favourably with values calculated through the use of (S-F) equation. The results show that the unperturbed dimensions are dependent on the solvent nature. © 1979.
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页码:685 / 687
页数:3
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