SYNTHESIS, CHARACTERIZATION, AND POLYMERIZATION OF PROPENYL ETHER ANALOGS

被引:5
作者
CRIVELLO, JV
CARTER, AM
BRATSLAVSKY, SA
机构
[1] Department of Chemistry, Rensselaer Polytchnic Institute, Troy, New York
关键词
PROPENYL ETHER ANALOGS; CATIONIC PHOTOPOLYMERIZATION; MONOMER SYNTHESIS;
D O I
10.1002/pola.1994.080321511
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A series of aromatic monomers bearing cationically polymerizable propenyl groups were prepared and characterized using the readily available starting materials: isoeugenol and o-allyl phenol. Monomers with both propenyl and vinyl ether functional groups were also synthesized by the reaction of these starting materials with chloroethyl vinyl ether. The reactivity of the resulting monomers in photoinitiated cationic polymerization was studied using differential scanning photocalorimetry and photogel point measurements. Their thermal properties were determined using thermogravimetric analysis. (C) 1994 John Wiley and Sons, Inc.
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页码:2895 / 2909
页数:15
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