A NOVEL AND MILD SOURCE OF CARBON-CENTERED RADICALS BY IODOSOBENZENE DIACETATE (IBDA) AND SODIUM-AZIDE FROM ALCOHOLS, ETHERS, ALDEHYDES, AMIDES AND ALKYL IODIDES

被引：75

作者：

FONTANA, F

MINISCI, F

YAN, YM

ZHAO, LH

机构：

[1] Dipartimento di Chimica del Politecnico, 20133 Milano, piazza Leonardo da Vinci

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 15期

关键词：

D O I：

10.1016/S0040-4039(00)60456-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A radical process occurs for the thermal decomposition of IBDA in the presence of sodium azide; by this method, carbon centered radicals can be generated either by hydrogen abstraction from the solvent (an alcohol, an ether, an aldehyde or formamide) or by iodine abstraction from alkyl iodides.

引用

页码：2517 / 2520

页数：4

共 11 条

[1] COPPA F, 1992, CHEM LETT, P1259
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MINISCI, F
FONTANA, F
VISMARA, E
[J]. JOURNAL OF HETEROCYCLIC CHEMISTRY, 1990, 27 (01) : 79 - 96
[3] POLAR EFFECTS IN FREE-RADICAL REACTIONS - NEW SYNTHETIC DEVELOPMENTS IN THE FUNCTIONALIZATION OF HETEROAROMATIC BASES BY NUCLEOPHILIC RADICALS
MINISCI, F
CITTERIO, A
VISMARA, E
GIORDANO, C
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[4] MINISCI F, 1963, TETRAHEDRON LETT, P357
[5] MINISCI F, 1962, TETRAHEDRON LETT, P533
[6] FREE-RADICAL ADDITIONS TO OLEFINS IN PRESENCE OF REDOX SYSTEMS
MINISCI, F
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1975, 8 (05) : 165 - 171
[7] A NEW GENERAL-METHOD OF HOMOLYTIC ALKYLATION OF PROTONATED HETEROAROMATIC BASES BY CARBOXYLIC-ACIDS AND IODOSOBENZENE DIACETATE
MINISCI, F
VISMARA, E
FONTANA, F
BARBOSA, MCN
[J]. TETRAHEDRON LETTERS, 1989, 30 (34) : 4569 - 4572
[8] RECENT DEVELOPMENTS OF FREE-RADICAL SUBSTITUTIONS OF HETEROAROMATIC BASES
MINISCI, F
VISMARA, E
FONTANA, F
[J]. HETEROCYCLES, 1989, 28 (01) : 489 - 519
[9] MINISCI F, 1967, CHIM IND-MILAN, V49, P706
[10] Minisci F., 1986, SUBSTITUENT EFFECTS, P391

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