A NOVEL AND MILD SOURCE OF CARBON-CENTERED RADICALS BY IODOSOBENZENE DIACETATE (IBDA) AND SODIUM-AZIDE FROM ALCOHOLS, ETHERS, ALDEHYDES, AMIDES AND ALKYL IODIDES

被引:75
作者
FONTANA, F
MINISCI, F
YAN, YM
ZHAO, LH
机构
[1] Dipartimento di Chimica del Politecnico, 20133 Milano, piazza Leonardo da Vinci
关键词
D O I
10.1016/S0040-4039(00)60456-2
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A radical process occurs for the thermal decomposition of IBDA in the presence of sodium azide; by this method, carbon centered radicals can be generated either by hydrogen abstraction from the solvent (an alcohol, an ether, an aldehyde or formamide) or by iodine abstraction from alkyl iodides.
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页码:2517 / 2520
页数:4
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