SYNTHESIS, X-RAY STRUCTURAL DETERMINATION AND COORDINATION CHEMISTRY OF 4'-FERROCENYL-2,2'/6',2''-TERPYRIDINE

被引：56

作者：

FARLOW, B

NILE, TA

WALSH, JL

MCPHAIL, AT

机构：

[1] UNIV N CAROLINA, DEPT CHEM, GREENSBORO, NC 27412 USA

[2] DUKE UNIV, DEPT CHEM, PAUL M GROSS CHEM LAB, DURHAM, NC 27706 USA

来源：

POLYHEDRON | 1993年 / 12卷 / 23期

关键词：

D O I：

10.1016/S0277-5387(00)80074-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

4'-Ferrocenyl-2,2':6',2''-terpyridine(Fctrpy) has been prepared from ferrocene carboxaldehyde and 2-acetylpyridine. A single crystal X-rav structure analysis indicates typical bond distances and angles with nearly coplanar aromatic rings. The angle between the cyclopentadienyl ring of the ferrocene moiety and the central pyridyl ring of the terpyridine is 19.2 Ruthenium complexes, Ru(Fctrpy)22+ and Ru(trpy) (Fctrpy)2+ (trpy = 2,2': 6',2''-terpyridine) have been prepared and characterized electrochemically and spectrophotometrically.

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页码：2891 / 2894

页数：4

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