HEXAKIS(BENZOTRIAZOLATO)TETRAKIS-(2,4-PENTANEDIONATO)PENTACOPPER(II) - A MODEL FOR CORROSION INHIBITION

被引：54

作者：

HANDLEY, J

COLLISON, D

GARNER, CD

HELLIWELL, M

DOCHERTY, R

LAWSON, JR

TASKER, PA

机构：

[1] UNIV MANCHESTER,DEPT CHEM,OXFORD RD,MANCHESTER M13 9PL,LANCS,ENGLAND

[2] ICI SPECIALTIES,RES CTR,MANCHESTER M9 3DA,ENGLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 07期

关键词：

D O I：

10.1002/anie.199310361

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Each benzotriazolato (bta) ligand is bound to three copper(II) ions in the penta-nuclear title complex. The known copper corrosion inhibitor, Hbta, might bind similarly to two metal atoms on the surface to be protected and one metal atom of the underlying layer. Results of molecular modeling studies suggest that the optimal interaction of bta- with the surfaces of Cu2O and CuO occurs for an orientation perpendicular to the (110) surface.

引用

页码：1036 / 1038

页数：3

共 13 条

[1] ADSORBED CORROSION-INHIBITORS STUDIED BY ELECTRON-SPECTROSCOPY - BENZOTRIAZOLE ON COPPER AND COPPER-ALLOYS [J].