HYDRORUTHENATION OF PROP-2-YNYLTRIPHENYLPHOSPHONIUM BROMIDE - SYNTHESIS, CRYSTAL-STRUCTURE AND REACTIONS OF [RUBR(CH=CHCH(2)PPH(3))(CO)(PPH(3))(2)]PF6

被引:16
作者
ALCOCK, NW
CARTWRIGHT, J
HILL, AF
MARCELLIN, M
RAWLES, HM
机构
[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,LONDON SW7 2AY,ENGLAND
[2] UNIV WARWICK,DEPT CHEM,COVENTRY CV4 7AL,W MIDLANDS,ENGLAND
关键词
D O I
10.1039/c39950000369
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The reaction of the complex [RuClH(CO)(PPh(3))(3)] with prop-2-ynyltriphenylphosphonium bromide ([Ph(3)PCH(2)C equivalent to CH]Br) followed by NH4PF6 provides the crystallographically characterised salt [RuBr(CH=CHCH(2)PPh(3))(CO)(PPh(3))(2)]PF6 which by virtue of the coordinative unsaturation at the ruthenium centre undergoes addition of the ligands CNC(6)H(3)Me(2)-2,6, and CO to Ru and insertion of SO2 into the Ru-C sigma-bond.
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页码:369 / 370
页数:2
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