ARYL EFFECTS AND ACIDITIES OF AMMONIA, TOLUENE, AND METHANE IN DIPOLAR NON-HYDROXYLIC SOLVENTS

被引：44

作者：

ALGRIM, D ^{[1
]}

BARES, JE ^{[1
]}

BRANCA, JC ^{[1
]}

BORDWELL, FG ^{[1
]}

机构：

[1] NORTHWESTERN UNIV,DEPT CHEM,EVANSTON,IL 60201

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1978年 / 43卷 / 26期

关键词：

D O I：

10.1021/jo00420a032

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

For a series of carbon acids, ArCHG and ArCH(CN)2, with G = C6H5, CN, COCH3, and NO2, the equilibrium acidities in Me2SO reveal a linear correlation between the Hammett p and the size of the Ph effect (ΔpK for Ar = Ph vs. Ar = H or Me). © 1978, American Chemical Society. All rights reserved.

引用

页码：5024 / 5026

页数：3

共 14 条

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[7] MEASURES OF GOODNESS OF FIT IN LINEAR FREE-ENERGY RELATIONSHIPS
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[8] Lagowski J., 1971, PURE APPL CHEM, V25, P429
[9] EQUILIBRIUM ACIDITIES OF CARBON ACIDS .6. ESTABLISHMENT OF AN ABSOLUTE SCALE OF ACIDITIES IN DIMETHYL-SULFOXIDE SOLUTION
MATTHEWS, WS
BARES, JE
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MCCOLLUM, GJ
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[10] MCCALLUM RW, UNPUBLISHED

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