PIGMENTS OF FUNGI .14. A DEGRADATIVE METHOD FOR THE DETERMINATION OF CENTRAL CHIRALITY IN NATURALLY-OCCURRING 3-HYDROXY-3-METHYL-3,4-DIHYDROANTHRACEN-1(2H)ONES

被引：16

作者：

GILL, M

GIMENEZ, A

JHINGRAN, AG

PALFREYMAN, AR

机构：

[1] Department of Organic Chemistry, University of Melbourne, Parkville

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 08期

关键词：

D O I：

10.1016/S0040-4039(00)88766-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Torosachrysone (2) is correlated over six steps without the need for intermediate purification with methyl R-(+)-tetrahydro-2-methyl-5-oxo-2-furanacetate (16); the method is applicable in principle to a large number of more complex dihydroanthracenones of as yet indeterminate stereochemistry. © 1990.

引用

页码：1203 / 1206

页数：4

共 11 条

[1]

BILLEN G, 1988, NATURAL PRODUCTS CHE, V3, P305

[2]

BURNS CJ, IN PRESS TETRAHEDRON

[3] A GREATLY IMPROVED PROCEDURE FOR RUTHENIUM TETRAOXIDE CATALYZED OXIDATIONS OF ORGANIC-COMPOUNDS [J].