METHYL-SUBSTITUTED 2-PICOLINAMINE N-OXIDE COMPLEXES OF COPPER(II) PERCHLORATE

被引：13

作者：

WEST, DX ^{[1
]}

KOHRMAN, RE ^{[1
]}

机构：

[1] CENT MICHIGAN UNIV,DEPT CHEM,MT PLEASANT,MI 48859

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1979年 / 41卷 / 04期

关键词：

D O I：

10.1016/0022-1902(79)80429-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cu(II) complexes of N-Methyl-2-picolinamine N-oxide (MA) and N,N-dimethyl-2-picolinamine N-oxide (DMA) have been prepared with Cu(II) perchlorate. Both the dull violet [Cu(MA)2](ClO4)2 and bright purple [Cu(DMA)2](ClO4)2 consist of two bidentate ligands in a square planar arrangement. IR, electronic and electron spin resonance spectra as well as molar conductivities and elemental analyses are presented as evidence for the essentially square planar geometry. © 1979.

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页码：477 / 480

页数：4

相关论文

共 19 条

[1]

BELLAMY LJ, 1962, INFRA RED SPECTRA CO, P251

[2] ELECTRONIC PROPERTIES AND STEREOCHEMISTRY OF COPPER(II) ION .7. MONO(DIETHYLENETRIAMINE)COPPER(II) COMPLEXES [J].

BEW, MJ ;

HATHAWAY, BJ ;

FEREDAY, RJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1972, (12) :1229-&

[3] CHARGE-TRANSFER SPECTRA OF PYRIDINE N-OXIDE METAL COMPLEXES . DETERMINATION OF OPTICAL ELECTRONEGATIVITIES [J].

BYERS, W ;

CHOU, BFC ;

LEVER, ABP ;

PARISH, RV .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (06) :1329-&

[4] EPR, NMR AND ABSORPTION SPECTROSCOPY STUDIES OF NI(II) AND CU(II) COMPLEXES WITH THR-LYS-ALA-ALA PEPTIDE IN AQUEOUS-SOLUTION [J].

FORMICKAKOZLOWSKA, G ;

KOZLOWSKI, H ;

JEZOWSKATRZEBIATOWSKA, B .

INORGANICA CHIMICA ACTA, 1977, 25 (01) :1-5

[5] 2-PYRDYLCARBINOL N-OXIDE COMPLEXES FROM TRANSITION-METAL ION TETRAFLUOROBORATES [J].

FRANK, CA ;

WEST, DX .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1977, 39 (05) :793-796

[6] USE OF CONDUCTIVITY MEASUREMENTS IN ORGANIC SOLVENTS FOR CHARACTERISATION OF COORDINATION COMPOUNDS [J].

GEARY, WJ .

COORDINATION CHEMISTRY REVIEWS, 1971, 7 (01) :81-&

[7] TRANSITION-METAL ION COMPLEXES OF 2-ACETYLPYRIDINE N-OXIDE [J].

HAGLEY, VS ;

KOHRMAN, RE ;

WEST, DX .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1977, 39 (11) :1959-1963

[8] METAL-COMPLEXES OF AROMATIC AMINE N-OXIDES [J].

KARAYANNIS, NM ;

PYTLEWSKI, LL ;

MIKULSKI, CM .

COORDINATION CHEMISTRY REVIEWS, 1973, 11 (02) :93-159

[9] INFRA-RED STUDIES OF PYRIDINE N-OXIDE AND ITS CO(II), NI(II), CU(II), ZN(II), AL(III), CR(III), FE(II), FE(III) AND SN(IV) COMPLEXES IN THE 3-15 MU-REGION [J].

KIDA, S ;

QUAGLIANO, JV ;

WALMSLEY, JA ;

TYREE, SY .

SPECTROCHIMICA ACTA, 1963, 19 (01) :189-199

[10] METAL-ION COMPLEXES OF 2-METHYLAMINOPYRIDINE N-OXIDE [J].

KOHRMAN, RE ;

PHADTARE, PG ;

WEST, DX .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1975, 37 (01) :301-303