APPLICATION OF AMPP-PD CATALYSTS IN AN UNUSUAL ASYMMETRIC ALLYLIC COUPLING REACTION OF 1-TRIMETHYLSILYL VINYL MAGNESIUM BROMIDE

被引:16
作者
FOTIADU, F [1 ]
CROS, P [1 ]
FAURE, B [1 ]
BUONO, G [1 ]
机构
[1] UNIV AIX MARSEILLE 3,FAC SCI & TECH ST JEROME,ECOLE SUPER CHIM MARSEILLE,URA 126,F-13397 MARSEILLE 13,FRANCE
关键词
D O I
10.1016/S0040-4039(00)94338-7
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Unusual palladium catalyzed allylation of a silylated Grignard reagent by cyclohexenyl acetate gives in high yields a versatile synthon, 3-(1-trimethyisilyl vinyl) cyclohexene; use of chiral AMPP ligands results in e.e. up to 33 %. © 1990.
引用
收藏
页码:77 / 80
页数:4
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