REACTIVITY PATTERNS OF H-2 AND CO WITH A RHODIUM(II) SALEN DERIVATIVE - FORMATION OF HYDRIDE, FORMYL, AND DIMETAL KETONE COMPLEXES AND RHODIUM REDUCTION

被引:23
作者
BUNN, AG [1 ]
WEI, ML [1 ]
WAYLAND, BB [1 ]
机构
[1] UNIV PENN,DEPT CHEM,PHILADELPHIA,PA 19104
关键词
D O I
10.1021/om00021a006
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A benzene soluble dimeric rhodium(II) salen derivative, [(ttbs)Rh](2), with a weak Rh-Rh bond (13 kcal mol(-1)) reacts with H-2 and CO to produce hydride, metalloketone, and formyl complexes, but reaction. of (ttbs)Rh-H with CO also induces migration. of H+ from rhodium to the salen ligand to form a rhodium(I) dicarbonyl complex, (Httbs)Rh(CO)(2).
引用
收藏
页码:3390 / 3392
页数:3
相关论文
共 24 条