DICHLORO-[N-(2-PYRIDYLMETHYLIDENE)-2-THIENYLMETHYLAMINE-N,N']COPPER(II) AND DIBROMO-[N-(2-PYRIDYLMETHYLIDENE)-2-THIENYLMETHYL-AMINE-N,N']COPPER(II) COMPLEXES, [CUCL2(C11H10N2S)] AND [CUBR2(C11H10N2S)]

被引：9

作者：

ATRIA, AM

BAGGIO, RF

ESPINOSA, N

GARLAND, MT

MANZUR, J

MORENO, Y

SPODINE, E

机构：

[1] COMIS NACL ENERGIA ATOM,DEPT FIS,DIV FIS SOLIDO,RA-1429 BUENOS AIRES,DF,ARGENTINA

[2] UNIV CHILE,FAC CIENCIAS FIS & MATEMAT,DEPT FIS,SANTIAGO,CHILE

[3] UNIV CHILE,FAC CIENCIAS FIS & MATEMAT,DEPT QUIM,SANTIAGO,CHILE

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1994年 / 50卷

关键词：

D O I：

10.1107/S0108270193012181

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structures of dichloro- (2) and dibromo[N-(2-pyridylmethylidene)-2-thienylmethylamine-N,N']copper(II) (1) have been determined to investigate the coordination of die metal centre. In both cases, the two N atoms and two halogen anions are coordinated to the copper(II) and the S atom is free. For the dibromo complex, the structure is monomeric, while die dichloro complex forms dimers (di-mu-chloro-bis{chloro[N-(2-pyridylmediylidene)-2-thienylmethyl-amine-N,N']copper(II)})

引用

页码：1066 / 1069

页数：4