PHOTOCHEMICAL SYNTHESES .I. FORMATION OF NAPHTHALENE-DIPHENYLACETYLENE PHOTO-ADDUCT

被引：25

作者：

SASSE, WHF

机构：

[1] Synthetic Chemistry Section, CSIRO Division of Applied Chemistry, Chatswood, NSW, 2067

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1969年 / 22卷 / 06期

关键词：

D O I：

10.1071/CH9691257

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The yield of the adduct in the light-induced naphthalene- diphenylacetylene addition depends inter alia on the concentrations of naphthalene and diphenyl-acetylene, and their ratio, the wavelengths of the incident light, and on the temperature of the reaction. The addition is retarded by oxygen and can be completely inhibited by benzophenone. A mechanism for the addition is discussed which involves the rearrangement of an exciplex derived from diphenylacetylene and singlet naphthalene. © 1969, CSIRO. All rights reserved.

引用

页码：1257 / &

共 29 条

[1] PHOTOCHEMICAL REACTIONS .12. ADDITION REACTIONS OF OLEFINS AND ACETYLENES WITH BENZONITRILE [J].