CHLORIDE-ION SUBSTITUTION IN ETA-5-CPRUCLL2 COMPLEXES AND THE FACILE CYCLOMETALATION OF A COMPLEXED TRIPHENYL PHOSPHITE AT A CATIONIC CYCLOPENTADIENYLRUTHENIUM CENTER

被引：33

作者：

JOSLIN, FL ^{[1
]}

MAGUE, JT ^{[1
]}

ROUNDHILL, DM ^{[1
]}

机构：

[1] TULANE UNIV,DEPT CHEM,NEW ORLEANS,LA 70118

来源：

ORGANOMETALLICS | 1991年 / 10卷 / 02期

关键词：

D O I：

10.1021/om00048a033

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex eta-5-cpRuCl(PPh3)2 (cp = cyclopentadienyl) reacts with trimethyl phosphite to give eta-5-cpRuCl(PPh3)(P(OMe)3). The complex crystallizes in the monoclinic space group P2(1)/n with a = 10.168 (1) angstrom, b = 16.622 (5) angstrom, c = 14.964 (2) angstrom, beta = 91.40 (1)-degrees, Z = 4, and 4151 data with I > 3-sigma(I); R = 0.025, R(w) = 0.038. The triphenyl phosphite analogue eta-5-cpRuCl(PPh3)(P(OPh)3) in THF solution reacts with silver triflate and piperidine at 25-degrees-C to give the cyclometalated complex eta-5-cpRu(PPh3)(P(OPh)2OC6H4).

引用

页码：521 / 524

页数：4

共 19 条

[1] CYCLOPENTADIENYL-RUTHENIUM AND CYCLOPENTADIENYL-OSMIUM CHEMISTRY .7. COMPLEXES CONTAINING NITRILES, TERTIARY PHOSPHINES OR PHOSPHITES FORMED BY ADDITION OR DISPLACEMENT-REACTIONS
ASHBY, GS
BRUCE, MI
TOMKINS, IB
WALLIS, RC
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1979, 32 (05) : 1003 - 1016
[2] BENNETT MA, 1982, CONPREHENSIVE ORGANO, V4
[3] SOME NEW PI-CYCLOPENTADIENYLRUTHENIUM COMPLEXES
BLACKMOR.T
BRUCE, MI
STONE, FGA
[J]. JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1971, (14): : 2376 - &
[4] CYCLOPENTADIENYL-RUTHENIUM AND CYCLOPENTADIENYL-OSMIUM CHEMISTRY .23. SYNTHESIS AND REACTIONS OF SOME HYDRIDO COMPLEXES CONTAINING RUTHENIUM OR OSMIUM, AND RELATED CHEMISTRY
BRUCE, MI
HUMPHREY, MG
SWINCER, AG
WALLIS, RC
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1984, 37 (08) : 1747 - 1755
[5] CYCLOPENTADIENYL-RUTHENIUM AND CYCLOPENTADIENYL-OSMIUM CHEMISTRY .4. CONVENIENT HIGH-YIELD SYNTHESIS OF SOME CYCLOPENTADIENYL RUTHENIUM OR OSMIUM TERTIARY PHOSPHINE HALIDE COMPLEXES
BRUCE, MI
WINDSOR, NJ
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1977, 30 (07) : 1601 - 1604
[6] CYCLOMETALLATION REACTIONS
BRUCE, MI
LIDDELL, MJ
PAIN, GN
BENNETT, MA
NEUMANN, H
[J]. INORGANIC SYNTHESES, 1989, 26 : 171 - 180
[7] CYCLOMETALATION REACTIONS
BRUCE, MI
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1977, 16 (02): : 73 - 86
[8] SOME "ETA-5-CYCLOPENTADIENYLRUTHENIUM(II) COMPLEXES CONTAINING TRIPHENYLPHOSPHINE
BRUCE, MI
HAMEISTER, C
SWINCER, AG
WALLIS, RC
[J]. INORGANIC SYNTHESES, 1982, 21 : 78 - 84
[9] CYCLOPENTADIENYL-RUTHENIUM AND CYCLOPENTADIENYL-OSMIUM CHEMISTRY .11. REACTIONS AND STRUCTURES OF [RUCL(PPH3)2(ETA-C5H5)] AND ITS TRIMETHYLPHOSPHINE ANALOG
BRUCE, MI
WONG, FS
SKELTON, BW
WHITE, AH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1981, (06): : 1398 - 1405
[10] CYCLOPENTADIENYL-RUTHENIUM AND CYCLOPENTADIENYL-OSMIUM CHEMISTRY .32. SOME COMPLEXES CONTAINING TERTIARY PHOSPHITES - X-RAY STRUCTURES OF RUCL(P(OME)3)2(ETA-C5H5) AND OF 2 ISOMERS OF RU(C[=C(CN)2]CPH=C(CN)2)(P(OME)3)2(ETA-C5H5)
BRUCE, MI
CIFUENTES, MP
SNOW, MR
TIEKINK, ERT
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 359 (03) : 379 - 399

← 1 2 →