A NEW SYNTHESIS OF SOLUBLE POLY(1,4-PHENYLENEVINYLENE)S AND POLY(2,5-PYRIMIDINYLENEVINYLENE)S

被引：39

作者：

KRETZSCHMANN, H ^{[1
]}

MEIER, H ^{[1
]}

机构：

[1] UNIV MAINZ,INST ORGAN CHEM,JJ BECHERWEG 18-22,W-6500 MAINZ,GERMANY

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 38期

关键词：

D O I：

10.1016/S0040-4039(00)93427-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alkoxy-substituted 4-methylbenzylideneanilines 2a-f and their pyrimidine analogues 2g,h show an efficient selfcondensation in the alkaline medium KOC(CH3)3/DMF. The totally stereoselective reaction yields 3a-h which are transformed by acidic work-up to 4a-h. A narrow distribution of the molecular weight can be achieved.

引用

页码：5059 / 5062

页数：4

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