ELECTROCHEMICAL AND SPECTROSCOPIC STUDY OF ANTHRACENE IN A MIXED LEWIS-BRONSTED ACID AMBIENT-TEMPERATURE MOLTEN-SALT SYSTEM

被引：18

作者：

CARLIN, RT ^{[1
]}

TRUELOVE, PC ^{[1
]}

OSTERYOUNG, RA ^{[1
]}

机构：

[1] SUNY BUFFALO,DEPT MED,BUFFALO,NY 14214

来源：

ELECTROCHIMICA ACTA | 1992年 / 37卷 / 14期

关键词：

MOLTEN SALTS; PULSE VOLTAMMETRY; NMR; ANTHRACENE; OXIDATION;

D O I：

10.1016/0013-4686(92)87061-4

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The electrochemistry, NMR and uv-vis spectroscopy of anthracene in ambient temperature molten salts composed of a mixture of AlCl3:1-ethyl-3-methylimidazolium chloride (ImCl) have been investigated. In acidic mixtures of AlCl3:ImCl, where the molar ratio is greater than 1, electrochemical oxidation of anthracene produces a cation radical which exhibits stability similar to that found in "super dry" dichloromethane. Electrochemical and spectroscopic measurements in the acidic melts show that anthracene protonates to form anthracenium cation. The anthracenium ion cannot be oxidized within the melt electrochemical window, but is reduced by yield H-2 and free anthracene. In basic mixtures of AlCl3:ImCl, where the molar ratio is less than 1, no anthracene electrochemistry is observed. However, NMR and uv-vis spectra in the basic melts show anthracene to be unprotonated.

引用

页码：2615 / 2628

页数：14

共 34 条

[1] [Anonymous], 1983, ADV MOLTEN SALT CHEM, DOI DOI 10.1039/B601395C
[2] CATHODIC REDUCTION OF ANTHRACENE IN LITHIUM CHLORIDE-HEXAMETHYLPHOSPHORAMIDE
AVACA, LA
BEWICK, A
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1972, (12): : 1709 - &
[3] Bard A. J., 1980, ELECTROCHEMICAL METH, P143
[4] BARD AJ, 1980, ELECTROCHEMICAL METH, P451
[5] DIFFERENTIAL NORMAL PULSE VOLTAMMETRY IN THE ALTERNATING PULSE MODE FOR REVERSIBLE ELECTRODE-REACTIONS
BRUMLEVE, TR
ODEA, JJ
OSTERYOUNG, RA
OSTERYOUNG, J
[J]. ANALYTICAL CHEMISTRY, 1981, 53 (04) : 702 - 706
[6] EBERSON L, 1991, ORGANIC ELECTROCHEMI, P505
[7] SUPERACID SOLUTIONS IN HYDROGEN-FLUORIDE
GILLESPIE, RJ
LIANG, J
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (18) : 6053 - 6057
[8] Gutmann V., 1978, DONOR ACCEPTOR APPRO
[9] REACTION OF ANTHRACENE CATION RADICAL WITH ACETONITRILE - NOVEL ANODIC ACETAMIDATION
HAMMERIC.O
PARKER, VD
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1974, (07) : 245 - 246
[10] THE MULTIPLICITY OF REACTION PATHWAYS OF CATION RADICALS DERIVED FROM ANTHRACENE-DERIVATIVES IN SOLVENTS OF LOW NUCLEOPHILICITY
HAMMERICH, O
PARKER, VD
[J]. ACTA CHEMICA SCANDINAVICA SERIES B-ORGANIC CHEMISTRY AND BIOCHEMISTRY, 1982, 36 (08): : 519 - 527

← 1 2 3 4 →