THE CHEMISTRY OF C-AROMATIC TAXANE DERIVATIVES ATROPISOMER CONTROL OF REACTION STEREOCHEMISTRY

被引:30
作者
JACKSON, RW [1 ]
HIGBY, RG [1 ]
GILMAN, JW [1 ]
SHEA, KJ [1 ]
机构
[1] UNIV CALIF IRVINE,DEPT CHEM,IRVINE,CA 92717
关键词
D O I
10.1016/S0040-4020(01)91211-6
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The atropselective synthesis of tricyclo [9.3.1.0(3,8)] pentadecane ring systems is reported. Substrate conformation is utilized for the stereoselective elaboration of functional groups. The conformational dynamics of intermediates are also reported.
引用
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页码:7013 / 7032
页数:20
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