METALATION OF ALKYNES .7. SUBSTITUENT EFFECTS IN ACETOXYMERCURATION OF 1-ARYLPROPYNES

被引：11

作者：

FLORIS, B

TASSONI, E

机构：

[1] Dipartimento di Scienze e Tecnologie Chimiche, Università di Roma “Tor Vergata”, 1-00133 Roma, Via della Ricerca Scientifica

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 12期

关键词：

D O I：

10.1021/om00024a021

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

1-Arylpropynes were added to mercuric acetate in acetic acid, with the regiochemistry depending on the substituent. Kinetics of acetoxymercuration were investigated. Second-order rate constants are best related by the Hammett sigma.

引用

页码：4746 / 4750

页数：5

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