CHEMICALLY BONDED STATIONARY PHASES THAT USE SYNTHETIC HOSTS CONTAINING AROMATIC BINDING CLEFTS - HPLC ANALYSIS OF NITROSUBSTITUTED POLYCYCLIC AROMATIC-HYDROCARBONS

被引：31

作者：

ZIMMERMAN, SC

SAIONZ, KW

ZENG, ZJ

机构：

[1] Department of Chemistry, University of Illinois, Urbana

[2] Research Institute of Scripps Clinic, San Diego

来源：

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA | 1993年 / 90卷 / 04期

关键词：

D O I：

10.1073/pnas.90.4.1190

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

The synthesis of hosts with improved binding affinities for nitroaromatic guests is described. Association constants for several host-guest complexes were measured in chloroform solution and ranged over three orders of magnitude. Two hosts were covalently linked to silica gel to produce chemically bonded stationary phases for HPLC. The use of these phases for HPLC analysis of nitro-substituted polycyclic aromatic hydrocarbons is discussed.

引用

页码：1190 / 1193

页数：4

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[1] MOLECULAR-STRUCTURES OF PORPHYRIN COMPLEXES IN SOLUTION - H-1 NUCLEAR MAGNETIC-RESONANCE SPECTROSCOPIC INVESTIGATION OF INTERACTION BETWEEN 2,4,7-TRINITROFLUORENONE AND NICKEL (II) AND COBALT(II) MESOPORPHYRIN IX DIMETHYL ESTERS [J].