COPPER(II) COMPLEXES AND BASIC PROPERTIES OF COCAINE

被引：5

作者：

NELSON, HC

WATT, GW

机构：

[1] Department of Chemistry, The University of Texas at Austin, Austin

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1979年 / 41卷 / 01期

关键词：

D O I：

10.1016/0022-1902(79)80402-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Despite extensive efforts employing a wide variety of techniques and procedures, solid metal ion complexes with cocaine and N-methylpiperidine, a model ligand for cocaine, were not isolated. Protonation constants and formation constants for the Cu(II) complexes of cocaine and N-methylpiperidine were determined potentiometrically at 30.0° and ionic strength approaching 0 in 50 vol. % dioxane-water solutions. © 1979.

引用

页码：99 / 102

页数：4

共 34 条

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ANDERSON CT, 1955, THESIS OHIO STATE U

[2]

BAILAR JC, 1956, CHEMISTRY COORDINATI, P62

[3] Acid-base studies in gaseous systems II The anomalous base strength of the methylamines, a new manifestation of steric strain [J].