OXIDATIVE DESULFURIZATION-FLUORINATION OF XANTHATES - A CONVENIENT SYNTHESIS OF TRIFLUOROMETHYL ETHERS AND DIFLUORO(METHYLTHIO)METHYL ETHERS

被引：87

作者：

KUROBOSHI, M ^{[1
]}

SUZUKI, K ^{[1
]}

HIYAMA, T ^{[1
]}

机构：

[1] SAGAMI CHEM RES CTR, 4-4-1 NISHIOHNUMA, SAGAMIHARA, KANAGAWA 229, JAPAN

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 29期

关键词：

OXIDATIVE DESULFURIZATION-FLUORINATION; XANTHATES; TRIFLUOROMETHYL ETHERS;

D O I：

10.1016/S0040-4039(00)74681-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of xanthates R-OC(S)SMe with (HF)9/Py and 1,3-dibromo-5,5-dimethylhydantoin gives trifluoromethyl ethers R-OCF3 through intermediates R-OCF2SMe, which could be isolated upon treatment of xanthates with n-Bu4N+H2F3- and N-bromosuccinimide.

引用

页码：4173 / 4176

页数：4

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