SIMPLE ONE-STEP SYNTHESIS OF 3-BROMO-1,10-PHENANTHROLINE AND 3,8-DIBROMO-1,10-PHENANTHROLINE - FUNDAMENTAL BUILDING-BLOCKS IN THE DESIGN OF METAL-CHELATES

被引：83

作者：

TZALIS, D ^{[1
]}

TOR, Y ^{[1
]}

FAILLA, S ^{[1
]}

SIEGEL, JS ^{[1
]}

机构：

[1] UNIV CALIF SAN DIEGO,DEPT CHEM & BIOCHEM,LA JOLLA,CA 92093

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 20期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0040-4039(95)00572-T

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Commercially available 1,10-phenanthroline monohydrochloride monohydrate (1) reacts with bromine to give 3-bromo-1,10-phenanthroline (2) and 3,8-dibromo-1,10-phenanthroline (3) as major products in a one step reaction.

引用

页码：3489 / 3490

页数：2

共 6 条

[1] SUBSTITUTED 1,10-PHENANTHROLINES .4. BROMO DERIVATIVES [J].

CASE, FH .

JOURNAL OF ORGANIC CHEMISTRY, 1951, 16 (06) :941-945

[2] POLY-HALOGENATION OF NITROGEN CONTAINING HETEROCYCLIC-COMPOUNDS .3. POLYBROMO-1,10-PHENANTHROLINES [J].

DENES, V ;

CHIRA, R .

JOURNAL FUR PRAKTISCHE CHEMIE, 1978, 320 (01) :172-175

[3]

GRAHAM B, 1958, CHEM HETEROCYCLIC CO, P386

[4]

KATRITZKY AR, 1990, ADV HETEROCYCL CHEM, V47

[5]

KRESS TJ, 1973, J HETEROCYCLIC CHEM, V10, P409, DOI 10.1002/jhet.5570100326

[6] 1,10-PHENANTHROLINE - A VERSATILE LIGAND [J].

SAMMES, PG ;

YAHIOGLU, G .

CHEMICAL SOCIETY REVIEWS, 1994, 23 (05) :327-334

← 1 →