STRUCTURE OF AMORPHOUS TA2O5.NH2O DERIVED FROM PEROXO-POLYTANTALATE SOLUTION

被引:9
作者
KISHIMOTO, A [1 ]
SUGIMOTO, H [1 ]
NANBA, T [1 ]
KUDO, T [1 ]
机构
[1] SCI UNIV TOKYO,FAC ENGN,SHINJYUKU KU,TOKYO 162,JAPAN
关键词
D O I
10.1016/0022-4596(91)90177-J
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The structure of tantalum oxide hydrate derived from peroxo poly-tantalate was investigated on the basis of XRD analyses. The peak positions in the pair distribution functions (PDF) for as-prepared and postannealed samples correspond with those calculated from the crystalline l-Ta2O5. Microcluster models for each sample were constructed and the validities of these models were confirmed by comparison between their calculated PDFs and their observed ones. © 1991.
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页码:102 / 108
页数:7
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