SYNTHESIS AND CRYSTAL AND MOLECULAR-STRUCTURE OF H3(MU-ETA-2-C6H4) (MU-ETA-2-HC3NC6H5)OS3(CO)8

被引：17

作者：

ADAMS, RD

GOLEMBESKI, NM

机构：

[1] Department of Chemistry, Yale University, New Haven

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 172卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)81051-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex H3(μ-η2-C6H4) (μ-η2-HC3NC6H5)Os3(CO)8 has been synthesized and characterized by IR, 1H NMR and X-ray crystal structure analyses. The compound contains a dihapto-benzyne ligand bridging one edge of a triangular cluster of osmium atoms and a dihapto-formimidoyl ligand bridging a different edge on the opposite face of the cluster from the benzyne ligand. © 1979.

引用

页码：239 / 249

页数：11

共 11 条

[1] ISOCYANIDE INSERTION REACTIONS - ROLE OF ISOCYANIDE INSERTIONS IN METAL ASSISTED HYDROGENATION OF ISOCYANIDES
ADAMS, RD
GOLEMBESKI, NM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (14) : 4622 - 4623
[2] ADAMS RN, UNPUBLISHED
[3] OXIDATIVE ADDITION-REACTIONS OF TRIPHENYLPHOSPHINE WITH DODECACARBONYL-TRIOSMIUM(O) - BENZENE-COMPLEXES, PHENYL-COMPLEXES AND RELATED COMPLEXES OF OSMIUM
BRADFORD, CW
MASON, R
GAINSFORD, GJ
GUSS, JM
NYHOLM, RS
IRELAND, PR
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1972, (02) : 87 - +
[4] OXIDATIVE ADDITION-REACTIONS OF TRIPHENYLPHOSPHINE WITH DODECACARBONYLTRIOSMIUM
BRADFORD, CW
NYHOLM, RS
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1973, (05): : 529 - 533
[5] NEUTRAL, CATIONIC, AND DICATIONIC RUTHENIUM(II) COMPLEXES OF SECONDARY CARBENES CHNH(P-C6H4CH3) AND CHN(CH3)(P-C6H4CH3)
CHRISTIA.DF
ROPER, WR
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1974, 80 (02) : C35 - C38
[6] OXIDATION OF ALCOHOL TO COORDINATED CARBOXYLATE WITH A DIOXYGEN COMPLEX OF RUTHENIUM - EXAMPLES OF REVERSIBLE HYDROGEN TRANSFER TO AN ISOCYANIDE LIGAND
CHRISTIAN, DF
CLARK, GR
WHITTLE, KR
WATERS, JM
ROPER, WR
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1972, (08) : 458 - +
[7] CHEMISTRY OF METAL-HYDRIDES .17. ISOCYANIDE INSERTION INTO PT-H BOND, AND FORMIMIDOYL LIGAND
CHRISTIAN, DF
CLARK, HC
STEPANIAK, RF
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1976, 112 (02) : 209 - 225
[8] CHRISTIAN DF, 1975, J CHEM SOC DA, P2556
[9] STEPWISE REDUCTION OF THIOCARBONYL LIGAND-HYDRIDE TRANSFER TO CS-THIOFORMYL, THIOFORMALDEHYDE, METHYLTHIOLATO, SECONDARY CARBENE, FORMYL AND IMINOFORMYL COMPLEXES OF OSMIUM
COLLINS, TJ
ROPER, WR
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 159 (01) : 73 - 89
[10] OXIDATIVE ADDITION-REACTIONS IN CLUSTER COMPLEXES OF OSMIUM - INTRACLUSTER REACTIONS OF BENZYNE AND A NOVEL PHENYL COMPLEX
GAINSFORD, GJ
MASON, R
IRELAND, PR
GUSS, JM
BRADFORD, CW
NYHOLM, RS
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1972, 40 (02) : C70 - +

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