TRANSITION-METAL COMPLEXES .8. AN UNUSUAL REARRANGEMENT OF A BUTADIENYL LIGAND VIA CYCLOMETALATION

被引：11

作者：

DENNINGER, U ^{[1
]}

SCHNEIDER, JJ ^{[1
]}

WILKE, G ^{[1
]}

GODDARD, R ^{[1
]}

KROMER, R ^{[1
]}

KRUGER, C ^{[1
]}

机构：

[1] MAX PLANCK INST KOHLENFORSCH,KAISER WILHELM PL 1,D-45470 MULHEIM,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 459卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)86088-Y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cp*Ni(eta1,eta2-C4HPh4) (Cp* = eta5-C5Me5) (1) was prepared by reacting Cp*Ni(acac) with 1,4-dilithium-1,2,3,4-tetraphenylbutadiendiyl and its structure determined by X-ray diffraction. Thermolysis of 1 in THF affords Cp*Ni(eta3-1-benzyl-2,3-diphenylindenyl) (2) and Cp*Ni(eta3-3-benzylyl-1,2-diphenylindene) (3). The structures of 2 and 3 were also determined by X-ray diffraction. A proposed mechanism of product formation is discussed.

引用

页码：349 / 357

页数：9

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