SYNTHESIS AND MOLECULAR-STRUCTURE OF THE 1ST MONOMERIC (THIOHYDROXY)STANNYL COMPLEX, RU(SNME2SH)I(CO)(CN[P-TOLY])(PPH3)2

被引：17

作者：

CLARK, GR ^{[1
]}

FLOWER, KR ^{[1
]}

ROPER, WR ^{[1
]}

WRIGHT, LJ ^{[1
]}

机构：

[1] UNIV AUCKLAND,DEPT CHEM,PRIVATE BAG 92019,AUCKLAND,NEW ZEALAND

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 10期

关键词：

D O I：

10.1021/om00034a011

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of Ru(SnMe3)Cl(CO)(CN[p-tolyl])-(PPh3)2 (1) with 1 equiv of iodine selectively cleaves one of the stannylmethyl groups to afford the rearranged product, Ru(SnMe2Cl)I(CO)(CN[p-tolyl])(PPh3)2 (2), where chloride has migrated from ruthenium to tin. Treatment of 2 with an excess of KOH produces the hydroxystannyl complex Ru(SnMe2OH)I(CO)(CN[p-tolyl])(PPh3)2 (3) and reaction between 3 and H2S affords Ru(SnMe2SH)I(CO)(CN[p-tolyl])(PPh3)2(4) which is the first example of a monomeric, (thiohydroxy)stannyl complex. The molecular geometry of 4 has been determined by a single crystal X-ray diffraction study.

引用

页码：3810 / 3811

页数：2

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