POLYMERIZATION IN NONUNIFORM LATEX-PARTICLES .2. KINETICS OF 2-PHASE EMULSION POLYMERIZATION

A new theory, based on the concept of nonuniform distribution of free radicals in polymerizing latex particles, has been developed for the kinetics of two‐phase emulsion polymerization reactions. This theory also takes into account the diffusion controlled termination and propagation reactions to describe the gel effect and limiting conversion. The kinetic model permits prediction of the distribution of free radicals in the two polymer phases and rate of polymerization as a function of reaction conditions. Experimental data for polystyrene/polymethyl methacrylate and polymethyl methacrylate/polystyrene (postformed polymer/preformed polymer) in the literature have been used to assess the proposed idea of nonuniform distribution of free radicals in the latex particle. Copyright © 1990 John Wiley & Sons, Inc.