CATALYTIC CYCLOPROPANATION WITH TRANSITION-METAL SALTS OF SOLUBLE POLYETHYLENE CARBOXYLATES

被引：54

作者：

BERGBREITER, DE

MORVANT, M

CHEN, B

机构：

[1] Department of Chemistry, Texas A and M University College Station

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 24期

关键词：

D O I：

10.1016/0040-4039(91)85070-L

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Syntheses of Rh(II) carboxylate salts of terminally functionalized polyethylene carboxylic acids are described. These polymer-bound transition metals are homogeneous catalysts for cyclopropanation of alkenes at 100-degrees-C and have activities and selectivities like transition metal acetates but are quantitatively recoverable at 25-degrees-C.

引用

页码：2731 / 2734

页数：4

共 16 条

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