ESR OF BIMETALLIC TRANSITION-METAL MOLECULES - MO AND W WITH CU, AG, AND AU

被引：15

作者：

HAMRICK, YM ^{[1
]}

VANZEE, RJ ^{[1
]}

WELTNER, W ^{[1
]}

机构：

[1] UNIV FLORIDA, CTR CHEM PHYS, GAINESVILLE, FL 32611 USA

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 181卷 / 2-3期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0009-2614(91)90354-C

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Earlier ESR spectroscopy of CrCu, CrAg, and CrAu molecules in argon matrices at 4K has been extended to Mo and W. MoCu, MoAg, MoAu, WCu, WAg, and WAu are all found to have 6-SIGMA ground states with zero-field splitting parameters, D, greater than about 2 cm-1. Hyperfine and nuclear quadrupole (in molecules containing Au-197) interactions were observed.

引用

页码：193 / 200

页数：8

共 19 条

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